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Bismuth

lead - bismuth - polonium
Sb
Bi
Uup  
 
 

General
Name, Symbol, NumberBismuth, Bi, 83
Chemical series Poor metals
Group, Period, Block15 (VA), 6 , p
Density, Hardness 9780 kg/m3, 2.25
Appearance lustrous
reddish white
Atomic properties
Atomic weight 208.98038 amu
Atomic radius (calc.) 160 (143) pm
Covalent radius 146 pm
van der Waals radius no data
Electron configuration [Xe]44f14 5d10 6s2 6p3
e- 's per energy level2, 8, 18, 32, 18, 5
Oxidation states (Oxide) 3, 5 (mildly acidic)
Crystal structure Rhombohedral
Physical properties
State of matter Solid
Melting point 544.4 K (520.3 °F)
Boiling point 1837 K (2847 °F)
Molar volume 21.31 ×10;10-6 m3/mol
Heat of vaporization 104.8 kJ/mol
Heat of fusion 11.3 kJ/mol
Vapor pressure 0.000627 Pa at 544 K
Speed of sound 1790 m/s at 293.15 K
Miscellaneous
Electronegativity 2.02 (Pauling scale)
Specific heat capacity 122 J/(kg×K);
Electrical conductivity 0.867 106/m ohm
Thermal conductivity 07.87 W/(m×K);
1st ionization potential 703 kJ/mol
2nd ionization potential 1610 kJ/mol
3rd ionization potential 2466 kJ/mol
4th ionization potential 4370 kJ/mol
5th ionization potential 5400 kJ/mol
6th ionization potential 8520 kJ/mol
Most stable isotopes
isoNAhalf-life DMDE MeVDP
207Bi{syn.}31.55 yε2.399207Pb
208Bi{syn.}3,368,000 yε2.880208Pb
209Bi100%(1.9±0.2) ×1019yα 205 Tl
SI units & STP are used except where noted.

Bismuth is a chemical element in the periodic table that has the symbol Bi and atomic number 83. This heavy, brittle, white crystalline trivalent poor metal has a pink tinge and chemically resembles arsenic and antimony. Most diamagnetic of all metals, bismuth has the lowest thermal conductivity of all the elements except mercury. Lead-free bismuth compounds are used in cosmetics and in medical procedures.

Table of contents
1 Notable characteristics
2 Applications
3 History
4 Occurrence
5 Reference
6 External links

Notable characteristics

It is a brittle metal with a pinkish hue with an iridescent tarnish. Among the heavy metalss, it is the heaviest and the only non-toxic. No other metal is more diamagnetic than bismuth, except mercury. This metal, which occurs in its native form, has a high electrical resistance and also has the highest Hall effect of any metal (that is, it has the greatest increase in electrical resistance when it is placed in a magnetic field). When heated in air bismuth burns with a blue flame and its oxide forms yellow fumes.

Before 2003, bismuth was thought to be the heaviest stable element. However, researchers at the Institut d'Astrophysique Spatiale in Orsay, France measured the alpha emission half-life of Bi-209 to be (1.9 ± 0.2) × 1019 years;, meaning that bismuth is not stable after all.

Applications

Bismuth oxychloride is extensively used in cosmetics and bismuth subnitrate and subcarbonate are used in medicine.

Some other uses are:

  • Strong permanent magnets can be made from the alloy bismanol (MnBiBi).
  • Many bismuth alloys have low melting points and are widely used for fire detection and suppression system safety devices.
  • Bismuth is used in producing malleable irons.
  • Bismuth is finding use as a catalyst for making acrylic fibers.
  • Also used as a thermocouple material.
  • A carrier for U-235 or U-233 fuel in nuclear reactors.
  • Bismuth has also been used in solders. The fact that bismuth and many of its alloys expand slightly when they freeze make them ideal for this purpose.
  • Bismuth subnitrate is a component of glazes that produces an iridescent luster finish.

In the early 1990s, research began on the evaluation of bismuth as a nontoxic replacement for lead in such uses as ceramic glazes, fishing sinkers, food processing equipment, free-machining brasses for plumbing applications, lubricating greases, and shot for waterfowl hunting.

History

Bismuth (New Latin bisemutum from German Wismuth, perhaps from weisse Masse, "white mass") was confused in early times with tin and lead due to its resemblance to those elements. Claude Geoffroy Junine showed in 1753 that this metal is distinct from lead.

Occurrence

The most important ores of bismuth are bismuthinite and bismite. Canada, Bolivia, Japan, Mexico, and Peru are major producers. Bismuth produced in the United States is obtained as a by-product of copper, gold, lead, silver, tin and especially lead ore processing. The average price for bismuth in 2000 was US 7.70 per kilogram.

Reference

External links


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Thermal Connection
Resource for information on thermal properties of metals and other materials. Provided by K & K Associate's .
http://www.tak2000.com/

The Copper Page
The Copper Data Center is a bibliographic database covering the technological and environmental literature on copper, brass and bronze. It is created and maintained by the Copper Development Association Inc.
http://www.copper.org/

Aluminum Association, Inc.
Trade association for U.S. producers of primary aluminum, recyclers and semi-fabricated aluminum products, also offering publications, aluminum statistics and audiovisuals.
http://www.aluminum.org/

Arris International Corporation
Provide a complete selection of rare earth and refractory metals as well as custom fabrications, single crystals and stable isotopes.
http://www.arris-intl.com

Bismuth Institute
Includes technical information on the physical properties and economic applications of bismuth.
http://www.bismuth.be/

Metals Supplier Online
Features the searchable inventory of 2200 metals suppliers and material property data on 5000 metals.
http://www.suppliersonline.com

NASA Space Science Headlines -- Microgravity Science Lab Results
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http://www.ssl.msfc.nasa.gov/newhome/headlines/msad17jul97_1.htm

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http://www.tpicast.com/vprocess.htm

International Zinc Association
The voice of the world zinc industry.
http://www.iza.com

Tantalum-Niobium International Study Center
Increasing awareness of tantalum and niobium and their properties, and promoting the use of the metals and their products.
http://www.tanb.org/

Adolfo Rios Pita's pages
Several pages dealing with metals, its ecological extraction and recycling.
http://www.geocities.com/CapeCanaveral/Hangar/3474/

Advanced Materials Associates
Metallurgical engineering and advanced materials technology training consultancy.
http://www.advancedmaterialsassoc.com/

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Archive4images is an sophisticated imaging database - acquire live images from different sources (e.g. microscopes, SEM or digital photo cameras) and store them within Archive4images' database. Easy image measurement and annotations. Create impressive reports with optional reporting tool ProCollage.
http://www.archive4images.com

Hendrix Group Inc.
Information on storage tanks, risk based inspection, corrosion photographs, failure analysis case histories, metals and alloy properties.
http://www.hghouston.com/tidbits.html

Diffusion Bonding of Titanium Metal Structures
Describes evolution of diffusion bonding technology from early laboratory experiments to production applications on the B-1B bomber and the Space Shuttle. Many applications developed over an eighteen year period are described.
http://www.user.lasercom.net/normajean/normajean

FAR Associates
Multi-wavelength pyrometry applied to real-world problems in development, manufacturing, and processing of traditional and advanced materials.
http://www.pyrometry.com/

Iron Casting Research Institute
ICRI serves iron foundry members through technology transfer. Offers a technical paper on Grey Iron metallurgy and properties, originally presented in 1969.
http://www.ironcasting.org/

Steel
Animated flash movie of the production process.
http://www.sidmar.be/CONTENT/2c.htm



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