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Soap

        

This article is about a common cleaning mixture. For other uses of the word Soap, see Soap (disambiguation).

Soap is a surfactant cleaning mixture used for personal or minor cleaning. It usually comes in solid mouldeded form. Synthetic detergents have superseded soap as a laundry aid.

Soaps are mixtures of sodium or potassium salts of fatty acids which can be derived from oils or fats by reacting them with an alkali (such as sodium or potassium hydroxide) at 80°-100 °C in a process known as saponification. The fats are hydrolyzed by the base, yielding glycerol and crude soap.

Table of contents
1 Purification and finishing
2 Use
3 Disadvantages
4 See also
5 External links

Purification and finishing

Reaction contains sodium chloride, sodium hydroxide, and glycerol. These impurities are removed by boiling the crude soap curds in water and re-precipitating the soap with salt.

Sand or pumice may be added to produce a soap.

Use

Although the word soap continues to be used informally in everyday speech and product labels, in practice nearly all kinds of "soap" in use today are actually synthetic detergents, which are less expensive, more effective, and easier to manufacture.

Soaps are useful for cleansing because soap molecules attach readily to both nonpolar molecules (such as grease or oil) and polar molecules (such as water). Although grease will normally adhere to skin or clothing, the soap molecules can attach to it as a "handle" and make it easier to rinse away.

(water soluble end)
CH3-(CH2)n - COONa

(fatty part)

The hydrocarbon ("fatty") portion dissolves dirt and oils, while the ionic end makes it soluble in water. Thus, it allows water to remove normally-insoluble matter.

The ancient world was generally innocent of soap; the Romans built baths, but did not use soap in them. According to Pliny the Elder, soap was invented by the ancient Gauls. They did not use it for washing, though; they used it as a pomade to keep their hair shiny.

Historically, soap was made in the home by mixing animal fats with lye. Because of the caustic lye, this was a dangerous procedure (perhaps more dangerous than any present-day home activities) which could result in serious chemical burns or even blindness. Before commercially-produced lye was commonplace, it was produced at home for soap making from the ashes of a wood fire.

In modern times, the use of soap has become universal in industrialized nations due to a better understanding of the role of hygiene in eliminating disease vectors such as germs. Manufactured bar soaps first became available in the late nineteenth century, and advertising campaigns in Europe and the United States helped to increase popular awareness of the relationship between cleanliness and health. By the 1950s, soap had gained public acceptance as an instrument of personal hygiene

Disadvantages

Nowadays soap has mostly been superseded by modern detergents.

Washing agents do not contain soap for cleaning fabric, but to reduce foaming.

The disadvantages of soap are:

  • Soap deprives the skin of oils
  • Soap reacts basically, which results in damage to the fabric:
    R-CO2-Na --H20--> R-CO2- + Na+ + H20 ----> R-COOH (=fatty acid) + OH- (basically)
  • Soap reacts with lime to insoluble deposit:
    2R-COO- + Ca2+ (lime) ----> Ca(R-COO)2

See also

External links


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Blue Aspen Originals
Instructions for cold process soap making, rebatching, swirling, and recipes.
http://www.blueaspenoriginals.com

Handcrafted Soap Net
Resources for soap makers. Includes supplier database, message forum, and chat room.
http://www.handcraftedsoap.org

Soap Naturally Web
Collection of resources and information about natural handmade soap. Recipes, photo archive, history of soapmaking, and soap making methods.
http://www.soapnaturally.org

Cabbey's Bath Salts, Balms, and Bubbles
Simple and easy home recipes for bath salts, balms, and bubble.
http://www.acplace.com/Crafts/bath.htm

Lather Land
Free soap recipes and directions to make bar soap at home.
http://members.aol.com/oelaineo/soapmaking.html

The Handcrafted Soap Makers Guild, Inc.
Professional trade organization for makers of handcrafted soap and bodycare products; resources, networking, annual conference, and newsletter.
http://www.soapguild.org/

Lovena's Soapmaking
Includes online tutorials for swirling and layering techniques for the Oven Hot Process method of soapmaking.
http://lovenaonline.com/soapmaking/index.html

Olympic Views
Beneficial for those new to soaping. Recipes, information, and links compiled by Kathy Miller.
http://millersoap.com/

Liquid Soapmaking
Instructions for making liquid soap.
http://essencesupply.com/liquid/liquidsoap.html

Luscious Body Soap
Instructions for making soap, with photographs.
http://girliemac.com/soap/

Soap Stop Handmade Herbal Soaps
Our soaps are designed and produced to leave your skin feeling soft, smooth and pampered. Each batch is carefully produced by using the finest and freshest of oils and botanicals.
http://www.soapstop.com/MainPages/Soaps.htm

Cranberry Lane Soap Instructions
Step by step soap and soapmaking instructions. Cold process method in detail.
http://www.cranberrylane.com/soapmaking.htm

Soapnuts Faq Library
Learn how to make soap, lotions, natural body products. Recipes, facts, help and chat room.
http://www.soapnuts.com/

Soap Teacher
Soap making instructions.
http://www.soapteacher.com/

Abigail's Country Craft Soap Making
Basic tips and recipes soap and toiletry making.
http://www.acplace.com/Natural/soaps.htm

About.com Soap Making
Features information about learning to make soap.
http://www.candleandsoap.about.com/hobbies/candleandsoap/

Pioneer Thinking
Step by step instructions to make your own homemade fragrant soaps. Many recipes with herbs, beeswax, and vegetable oils.
http://www.pioneerthinking.com/soaps.html

Cole Brothers Soap
Guide on making and marketing decorative soap. Comes with 250 recipes and complete step by step instructions.
http://www.colebrothers.com/soap

Pine Meadows Soapmaking Recipes
Recipe listing includes soap, lotion, bath fizzies, lip balms, bath salts, body scrubs. Also includes scent blending suggestions.
http://www.pinemeadows.net/recipes.php

Soap Center
Soapmaking recipes, instructions, tips, and supplier links.
http://www.halderman.net/soap/

Teach Soap
Basic instructions for melt and pour, and cold process soap. Includes a glossary of soap making terms.
http://www.teachsoap.com/

All About Soapmaking
Learn all about making soap at home. Step by step instruction for Cold Process and Hot Process soap making. Also includes recipes and saponification table.
http://www.geocities.com/soapbubbles54

Audrey's Soap Site
Instruction and recipes for making soap at home. Also includes instruction and recipes for making your own cosmetics.
http://www.eaudrey.com/

How to Make Soap at Home
Soap, lotion, and toiletry making instructions. Recipes for goldfish in a bag soap and other glycerin melt and pour recipes. Also includes cold process soap instruction.
http://www.meltandpour.com/

GreenSense- Zenda's Homemade Soap and Beauty Recipes
Tips and recipes for homemade soap and beauty products.
http://www.greensense.com/ZENDA.HTM

Old-Timer's Soap Making
Old-time soap making instructions and links to further resources.
http://www.waltonfeed.com/old/soaphome.html

Soapmaking
How to make soap and other toiletries from scratch. Includes links, articles, and discussions.
http://www.suite101.com/welcome.cfm/soapmaking

Soap Making Business
Resources for those who want to start or grow a handcrafted bath and body care business.
http://www.soapmakingbusiness.com

Soap Recipes
User submitted recipes for homemade soap, bath salts, fizzies, scent combinations, and packaging tips.
http://www.geocities.com/soaprecipes

Luxury Lane
Hundreds of recipes for soap, and toiletries. Among these are recipes for soap, lotions, powders, scrubs, and liquid soap.
http://www.luxurylane.com

Make Your Cosmetics
Recipes and tips for making soap, toiletries, and cosmetics using natural ingredients.
http://www.makeyourcosmetics.com



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